| Titre : | Inorganic structural chemistry |
| Auteurs : | Ulrich M¼ller |
| Type de document : | Monographie imprimée |
| Mention d'édition : | 2nd ed. |
| Editeur : | John Wiley & Sons Inc, 2007 |
| ISBN/ISSN/EAN : | 978-0-470-01864-4 |
| Format : | x, 268 p. / fig., tabl |
| Langues: | Anglais |
| Résumé : |
This series reflects the pivotai rote of modern inorganic and physical chemistry in a whole range of emerging areas, such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in estabiished areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry. Cover design by Dan Jubb |
| Sommaire : |
Preface xi 1 Introduction 1 2 Description of Chemical Structures 2 2.1 Coordination Numbers and Coordination Polyhedra 3 2.2 Description of Crystal Structures 7 2.3 Atomic Coordinates 9 2.4 Isotypism 10 2.5 Problems 11 3 Symmetry 12 3.1 Symmetry Operations and Symmetry Elements 12 3.2 Point Groups 15 3.3 Space Groups and Spa ce-Group Types 20 3.4 Positions 22 3.5 Crystal Classes and Crystal Systems 24 3.6 Aperiodic Crystals 25 3.7 Disordered Crystals 27 3.8 Problems 28 4 Polymorphism and Phase Transitions 30 4.1 Thermodynamic Stability 30 4.2 Kinetic Stability 30 4.3 Polymorphism 31 4.4 Phase Transitions 32 4.5Phase Diagrams 34 4.6 Problems 38 5 Chemical Bonding and Lattice Energy 39 5.1 Chemical Bonding and Structure 39 5.2 Lattice Energy 40 5.3 Problems 44 6 The Effective Size of Atoms 45 6.1 Van der Waals Radii 46 6.2Atomic Radii in Metals 46 6.3 Covalent Radii 47 6.4 Ionic Radii 48 6.5 Problems 51 Ionie Compounds 52 7.1 Radius Ratios 52 7.2 Ternary Ionie Compounds 55 7.3 Compounds with Complex Ions 56 7.4 The Rules of Pauling and Baur 58 7.5 Prohlems 61 8 Molecular Structures I: Compounds of Main Croup Elements 62 8.1 Valence Sheli Electron-Pair Repulsion 62 8.2 Structures with Five Valence Electron Pain 71 8.3 Problems 72 9 Molecular Structures II: Compounds of Transition Metals 73 9.1 Ligand Field Theory 73 9.2 Ligand Field Stahilization Energy 77 9.3 Coordination Polyhedra for Transition Metals 80 9.4 Isomerism 81 9.5 Problems 84 10 Molecular Orbital Theory and Chemical Bonding in Solids 85 10.1 Molecular Orbitals 85 10.2 Hybridization 87 10.3 The Electron Localisation Function 89 10.4 Band Theory. The Linear Chain of Hydrogen Atoms 90 10.5 The Peierls Distortion 93 10.6 Crystal Orbital Overlap Population (COOP) 96 10.7 Bonds in Two and Three Dimensions 99 10.8 Bonding in Metals loi 10.9 Problems 102 11 The Element Structures of the Nonmetals 103 I I . I Hydrogen and the Halogens 103 1 I .2 Chalcogens I05 11.3 Elements of the Fifth Main Group 107 i I .4 Elements of the Fifth and Si xth Main Groups under Pressure I 1 1 1 I .5 Carbon 1 I 3 1 1 .6 Boron 116 12 Diamond-like Structures 118 12.1 Cuhic and Hexagonal Diamond I I S 12.2 Binary Diamond-like Compounds 1 1 12.3 Diamond-like Compounds under Pressure 120 12.4 Polynary Diamond-like Compounds 123 12.5 Widened Diamond Lattices. SiO, Structures 124 12.6 Prohlems 127 13 Polyanionic and Polycationic Compounds. Zintl Phases 128 13.1 The Gcneralized 8 - N Rule 128 13.2 Polyanionic Compounds, Zintl Phases 130 13.3 Polycationic Compounds 137 13.4 Cluster Compounds 138 13.5 Prohlems 149 14 Packings of Spheres. Metal Structures 150 14.1 Closest-packings of Spheres 150 14.2 Body-centered Cubic Packing of Spheres 153 14.3 Other Metal Structures 154 14.4 Problems 155 15 The Sphere-packing Principle for Compounds 157 15.1 Ordcred and Disordered Alloys I 57 15.2 Compounds with Close-packed Atoms I58 15.3 Structures Derived of Body-centered Cubic Packing (CsCI Type) 160 15.4 Hume-Rothery Phases 161 15.5 Laves Phases 162 15.6 Problems 165 16 Linked Polyhedra 166 16. I Vertex-sharing Octahedra 16.2 Edge-sharing Octahedra .713 16.3 Face-sharing Octahedra 175 16.4 Octahedra Sharing Vertices and Edges 176 16.5 Octahedra Sharing Edges and Faces 179 16.6 Linked Trigonal Prisms 180 16.7 Vertex-sharing Tetrahedra. Silicates 180 16.8 Edge-sharing Tetrahedra 188 16.9 Prohlems 189 17 Packings of Spheres with Occupied Interstices 190 17.1 The Interstices in Closest-packings of Spheres 190 17.2 Interstitial Compounds 194 17.3 Structure Types with Occupied Octahedral Interstices in Closest-packings of Spheres . . 195 17.4 Perovskites 202 17.5 Occupation of Tetrahedral Interstices in Closest-packings of Spheres 206 17.6 Spinels 208 17.7 Problems 211 18 Symmetry as the Organizing Principle for Crystal Structures 212 18.1 Crystallographic Group-Subgroup Relations 212 18.2 The Symmetry Principle in Crystal Chemistry 214 18.3 Structural Relationships hy Group-Subgroup Relations 215 18.4 Symmetry Relations at Phase Transitions. Twinned Crystals 221 18.5 Problems 225 19 Physical Properties of Solids 226 19.1 Mechanical Properties 226 19.2 Piezoelectric and Ferroelectric Properties 227 19.3 Magnetic Properties 211 20 Nanostructures 241 21 Pitfalls and Linguistic Aberrations 246 References 249 Answers to the Problems 256 Index 259 |
Disponibilité (1)
| Cote | Support | Localisation | Statut |
|---|---|---|---|
| CH/240 | Livre | bibliothèque sciences exactes | Consultable |
